CRYSTAL-STRUCTURE AND SPECTROSCOPIC PROPERTIES OF A POLYNUCLEAR COMPLEX BETWEEN [BIS(2-AMINOETHYL)AMINE]COPPER(II) AND HEXACYANOFERRATE(III)

被引：48

作者：

MORPURGO, GO ^{[1
]}

MOSINI, V ^{[1
]}

PORTA, P ^{[1
]}

DESSY, G ^{[1
]}

FARES, V ^{[1
]}

机构：

[1] CNR, TEORIA STRUTTURA ELETTRONICA & COMPORTAMENTO SPETT, I-00131 ROME, ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1981年 / 01期

关键词：

D O I：

10.1039/dt9810000111

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of [Fe(CN)6]3- to [Cu(dien)]2+ [dien = diethylenetriamine, bis(2-aminoethyl)amine] [model for Cu-containing enzymes] gives a polynuclear complex of formula 3[Cu(dien)]2+.cntdot.2[Fe(CN)6]3-.cntdot.6H2O. The compound was characterized by IR, ESR and reflectance spectra, and its crystal and molecular structure solved by single-crystal X-ray diffractometry.

引用

页码：111 / 117

页数：7

共 27 条

[1] FORMATION OF MU-CYANO SPECIES IN REACTIONS BETWEEN BIS(HISTIDINATO) COBALT AND HEXACYANOFERRATE COMPLEXES [J].

BAGGER, S ;

GIBSON, K .

ACTA CHEMICA SCANDINAVICA, 1973, 27 (09) :3227-3233

[2] ELECTRONIC PROPERTIES AND STEREOCHEMISTRY OF COPPER(II) ION .7. MONO(DIETHYLENETRIAMINE)COPPER(II) COMPLEXES [J].

BEW, MJ ;

HATHAWAY, BJ ;

FEREDAY, RJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (12) :1229-&

[3]

BEW MJ, 1970, CHEM COMMUN, P887

[4]

Bleksza D.S., 1977, INORG CHEM, V16, P924

[5] CHARGE TRANSFER PHENOMENA IN SOME INORGANIC COMPLEXES .3. ULTRAVIOLET SPECTRA OF TRANSITION-METAL DERIVATIVES OF IRON GROUP CYANIDE COMPLEX ANIONS [J].

BRATERMA.PS .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (10) :1471-&

[6] CRYSTAL-STRUCTURES OF THIOCYANATE POLYAMINE COPPER(II) COMPLEXES .3. [J].

CANNAS, M ;

CARTA, G ;

MARONGIU, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (06) :553-555

[7] INVESTIGATION OF ROLE OF COPPER IN GALACTOSE OXIDASE [J].

CLEVELAND, L ;

COFFMAN, RE ;

COON, P ;

DAVIS, L .

BIOCHEMISTRY, 1975, 14 (06) :1108-1115

[8] SUPEROXIDE-DISMUTASE ACTIVITY OF GALACTOSE OXIDASE [J].

CLEVELAND, L ;

DAVIS, L .

BIOCHIMICA ET BIOPHYSICA ACTA, 1974, 341 (02) :517-523

[9] ANOMALOUS DISPERSION CORRECTIONS COMPUTED FROM SELF-CONSISTENT FIELD RELATIVISTIC DIRAC-SLATER WAVE FUNCTIONS [J].

CROMER, DT .

ACTA CRYSTALLOGRAPHICA, 1965, 18 :17-&

[10] X-RAY SCATTERING FACTORS COMPUTED FROM NUMERICAL HARTREE-FOCK WAVE FUNCTIONS [J].

CROMER, DT ;

MANN, JB .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :321-&

← 1 2 3 →