ELECTROSTATICS OF DIFFUSE ANISOTROPIC INTERFACES .2. EFFECTS OF LONG-RANGE DIFFUSENESS

被引：26

作者：

BUFF, FP

GOEL, NS

机构：

[1] Department of Chemistry, University of Rochester, Rochester

[2] Department of Physics and Astronomy, University of Rochester, Rochester

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 12期

关键词：

D O I：

10.1063/1.1671957

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Within the framework of macroscopic continuum theory, we formulate the calculation of the electrostatic potential for a charge in the presence of an anisotropic diffuse interface. We present a systematic method for determining the analytical forms of dielectric profiles for which the Fourier-Bessel components of the electrostatic potential can be obtained analytically. We discuss in detail a smooth exponential profile which manifests long-range diffuseness. On the basis of exact and approximate calculations, the image potential for this model is obtained in the main region of interest for applications.

引用

页码：5363 / &

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