CONTRIBUTIONS TO THE CHEMISTRY OF TRANSITION-METAL ALKYL-COMPOUNDS .57. 2-(DIMETHYLAMINOMETHYL)FERROCENYL COMPOUNDS OF 3 D ELEMENTS

被引：14
|
作者：
JACOB, K
KRETSCHMER, W
THIELE, KH
PAVLIK, I
LYCKA, A
HOLECEK, J
机构：
[1] TH CARL SCHORLEMMER LEUNA MERSEBURG,INST ANORGAN CHEM,GEUSAER STR,O-4200 MERSEBURG,GERMANY
[2] CHEM TECH HSCH PARDUBICE,LEHRSTUHL ALLGEMEINE & ANORGAN CHEM,CS-53210 PARDUBICE,CZECHOSLOVAKIA
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 606卷 / 15期
关键词：
2-(DIMETHYLAMINOMETHYL)FERROCENYL 3 D METAL COMPOUNDS; PREPARATION;
D O I：
10.1002/zaac.19916060114
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[2-(Dimethylaminomethyl)ferrocenyl]lithium, (FcN)Li (I), reacts with MCl2 . xTHF to (FcN)2Mn (II), (FcN)2Co (III), Li2[Fe(FcN)2Cl2] (IV) as well as with FeCl3 to (FcN)3Fe (V). In the same way the complex (C5H5)2V(FcN) (VI) was obtained from (C5H5)2VCl. When I is reacted with M(acac)3 (M = Cr, Co) only a partial ligand exchange took place - independently from the molar ratio of the reactants - with formation of (FcN)Cr(acac)2 (VII) and (FcN)Co(acac) (VIII). An intensive characterization of II-VIII was achieved by elementary analysis, determination of molecular weights, IR-, UV-VIS- and H-1-NMR spectra as well as determination of effective magnetic moments.
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页码：133 / 139
页数：7
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