CONTRIBUTIONS TO THE CHEMISTRY OF TRANSITION-METAL ALKYL-COMPOUNDS .57. 2-(DIMETHYLAMINOMETHYL)FERROCENYL COMPOUNDS OF 3 D ELEMENTS

被引：14

作者：

JACOB, K

KRETSCHMER, W

THIELE, KH

PAVLIK, I

LYCKA, A

HOLECEK, J

机构：

[1] TH CARL SCHORLEMMER LEUNA MERSEBURG,INST ANORGAN CHEM,GEUSAER STR,O-4200 MERSEBURG,GERMANY

[2] CHEM TECH HSCH PARDUBICE,LEHRSTUHL ALLGEMEINE & ANORGAN CHEM,CS-53210 PARDUBICE,CZECHOSLOVAKIA

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 606卷 / 15期

关键词：

2-(DIMETHYLAMINOMETHYL)FERROCENYL 3 D METAL COMPOUNDS; PREPARATION;

D O I：

10.1002/zaac.19916060114

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[2-(Dimethylaminomethyl)ferrocenyl]lithium, (FcN)Li (I), reacts with MCl2 . xTHF to (FcN)2Mn (II), (FcN)2Co (III), Li2[Fe(FcN)2Cl2] (IV) as well as with FeCl3 to (FcN)3Fe (V). In the same way the complex (C5H5)2V(FcN) (VI) was obtained from (C5H5)2VCl. When I is reacted with M(acac)3 (M = Cr, Co) only a partial ligand exchange took place - independently from the molar ratio of the reactants - with formation of (FcN)Cr(acac)2 (VII) and (FcN)Co(acac) (VIII). An intensive characterization of II-VIII was achieved by elementary analysis, determination of molecular weights, IR-, UV-VIS- and H-1-NMR spectra as well as determination of effective magnetic moments.

引用

页码：133 / 139

页数：7

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