NMR SPECTRUM OF ETHENE IN A NEMATIC SOLVENT

被引：18

作者：

BOVEE, W

HILBERS, CW

MACLEAN, C

机构：

[1] Chemical Laboratory of the Free University, Amsterdam

来源：

MOLECULAR PHYSICS | 1969年 / 17卷 / 01期

关键词：

D O I：

10.1080/00268976900100801

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The N.M.R. spectrum of ethene, oriented in the nematic phase of 4,4′-di-n-hexyloxyazoxybenzene, has been measured and interpreted. The absolute signs of the indirect coupling constants and the ratio x = rcis/trgem have been determined. This ratio is compared with data derived from electron diffraction, infra-red and Raman spectroscopy. The agreement is satisfactory. A discussion is given of vibrational corrections; the importance of anharmonicity is stressed. © 1969 Taylor and Francis Group, LLC.

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页码：75 / &

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