SOLUBILITIES OF ETHANOL, 1-PROPANOL, 2-PROPANOL AND 1-BUTANOL IN SUPERCRITICAL CARBON-DIOXIDE AT 313-K AND 333-K

被引：59

作者：

SUZUKI, T

TSUGE, N

NAGAHAMA, K

机构：

[1] Department of Industrial Chemistry, Tokyo Metropolitan University, Hachioji, Tokyo, 192-03

来源：

FLUID PHASE EQUILIBRIA | 1991年 / 67卷

关键词：

D O I：

10.1016/0378-3812(91)90057-E

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Using a flow-type apparatus for supercritical fluid extraction, solubilities of an alcohol in supercritical CO2 have been measured at 313 K and 333 K up to 11 MPa. Ethanol, 1-propanol, 2-propanol and 1-butanol were selected as the alcohols. Consistency of the obtained solubility data was tested by the enhancement factor method, which showed good consistency for all systems. The logarithmic values of the enhancement factors for all the alcohols were observed to be linear functions of pure CO2 density. Employing this linear relationship, the solubility of an alcohol in supercritical CO2 can easily be determined with high accuracy.

引用

页码：213 / 226

页数：14

共 12 条

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