PERMEABILITY, SOLUBILITY AND DIFFUSION OF GASES IN AMORPHOUS AND CRYSTALLINE 1,4-POLYBUTADIENE MEMBRANES

被引：25

作者：

COWLING, R

PARK, GS

机构：

[1] Chemistry Department, University of Wales, Institute of Science and Technology, Cardiff

来源：

JOURNAL OF MEMBRANE SCIENCE | 1979年 / 5卷 / 02期

关键词：

D O I：

10.1016/S0376-7388(00)80448-2

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Permeability, diffusion and solubility coefficients of hydrogen, neon, nitrogen, and carbon dioxide have been determined in amorphous (48% trans) and crystalline (90% trans) 1,4-polybutadiene in the temperature range from 15 to 65° C. The effects of crystallinity on transport estimated by the solubility coefficient ratios (S90% trans/S48% trans) and the diffusion coefficient ratios (D90%trans/D48% trans) are greater than for some larger diffusants studied previously. A mesomorphic (crystal/crystal) transition at about 45° C in the 90% trans polymer produces a sudden increase in the permeability with increasing temperature. © 1979.

引用

页码：199 / 207

页数：9

共 12 条

[1]

Barrer R. M., 1965, J POLYMER SCI C, V10, P111

[2] PERMEATION THROUGH A MEMBRANE WITH MIXED BOUNDARY CONDITIONS [J].

BARRER, RM ;

BARRIE, JA ;

ROGERS, MG .

TRANSACTIONS OF THE FARADAY SOCIETY, 1962, 58 (DEC) :2473-&

[3] TRANSPORT AND EQUILIBRIUM PHENOMENA IN GAS ELASTOMER SYSTEMS .1. KINETIC PHENOMENA [J].

BARRER, RM ;

SKIRROW, G .

JOURNAL OF POLYMER SCIENCE, 1948, 3 (04) :549-563

[4]

BROWN WR, 1973, J POLYM SCI POLYM S, V41, P45

[5]

DANUSSO F, 1967, POLYM, V8, P303

[6]

GEE G, 1947, Q REV CHEM SOC, V1, P295

[7]

IWAYANAGI S, 1965, REPT PROGR POLYM PHY, V8, P303

[8]

JENKINS RB, 1976, THESIS U WALES

[9]

JENKINS RB, 1974, 23 IUPAC INT S MACR, P5

[10]

Natta G., 1956, ATTI ACCAD NAZL SFMN, V20, P728

← 1 2 →