ELECTROCHEMICAL REDUCTION AND ELECTRON-SPIN RESONANCE STUDIES OF ORGANOZINC COMPLEXES

被引：13

作者：

ELSHAZLY, MF ^{[1
]}

机构：

[1] UNIV ALEXANDRIA,FAC SCI,SCI CTR ADVANCEMENT POST GRAD STUDIES,DEPT CHEM,ALEXANDRIA,EGYPT

来源：

INORGANICA CHIMICA ACTA | 1978年 / 26卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)87209-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electrochemical behaviour of organozinc compexes with di-2-pyridylketone, 1,2-bipyridine and 1,10-phenanthroline as ligands were investigated. The complexes showed two reductive waves in 1,2.dimethoxyethane (DME) as a solvent and tetrabutylammonium ammonium perchlorate (TBAP) as a supporting electrolyte. Controlled potential electrolysis at the plateau of the first wave produced coloured radical anions. The esr spectra of the radical anions showed that the unpaired electron is delocalized mainly over the ligand π-system. © 1978.

引用

页码：173 / 176

页数：4

共 13 条

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[7] DESSY RE, UNPUBLISHED
[8] DUNN MF, 1975, STRUCT BONDING BERLI, V23, P61
[9] ELSHAZLY MF, 1972, THESIS VIRGINIA POLY
[10] ELECTRON-SPIN RESONANCE STUDIES OF REDUCTION OF TRANSITION-METAL COMPLEXES WITH GRIGNARD-REAGENTS .1. DIANION RADICALS OF BETA-DIKETONATES
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