Bis(dicyanamido-kappa N)[tris(3-aminopropyl)amine-kappa N-4]nickel(II)

被引:0
作者
Luo, Jun [1 ]
Zhang, Xin-Rong [1 ]
Qiu, Li -Juan [1 ]
Yang, Feng [1 ]
Liu, Bao-Shu [1 ]
机构
[1] Second Mil Med Univ, Sch Pharm, Shanghai 200433, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1107/S1600536813015651
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Ni(C2N3)(2)(C9H24N4)], the Ni II atom is coordinated in a distorted octahedral geometry by one tris(3-aminopropyl) amine (trisapa) ligand and two dicyanamide (dca)ligands [ one of them disordered in a 0.681 (19):0319 (19) ratio]. Intermolecular N-H center dot center dot center dot N hydrogen bonds involving the N atoms of the dca anions and the trisapa amine H atoms result in the formation of a three- dimensional network.
引用
收藏
页码:M385 / +
页数:10
相关论文
共 17 条
[1]  
Batten S. R., 1998, J CHEM SOC CHEM COMM, P439
[2]   Glorious uncertainty - challenges for network design [J].
Batten, SR .
JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (08) :2475-2479
[3]   Structure and magnetism of coordination polymers containing dicyanamide and tricyanomethanide [J].
Batten, SR ;
Murray, KS .
COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :103-130
[4]   Syntheses, structures and magnetic properties of μ1,5 dicyanamide bridged coordination polymers of copper(II) and nickel(II) containing a tetradentate N-donor Schiff base [J].
Bhar, Kishalay ;
Chattopadhyay, Soumi ;
Khan, Sumitava ;
Kumar, Ramachandra Krishna ;
Maji, Tapas Kumar ;
Ribas, Joan ;
Ghosh, Barindra Kumar .
INORGANICA CHIMICA ACTA, 2011, 370 (01) :492-498
[5]   Nickel(II) complexes with dicyanamide and tetramines [J].
Brezina, F ;
Trávnícek, Z ;
Sindelár, Z ;
Pastorek, R ;
Marek, J .
TRANSITION METAL CHEMISTRY, 1999, 24 (04) :459-462
[6]  
Bruker, 2000, SMART SAINT SADABS
[7]   Trans-bis(dicyanamido)nickel(II) complexes with polyaza macrocyclic ligands [J].
Cho, JH ;
Lee, U ;
Kim, JC .
TRANSITION METAL CHEMISTRY, 2002, 27 (04) :429-432
[8]   CuII2L based polymeric ladder using dicyanamide bridges: Synthesis, crystal structure and magnetic studies [J].
Fondo, Matilde ;
Garcia-Deibe, Ana M. ;
Ocampo, Noelia ;
Vicente, Ramon ;
Sanmartin, Jesus ;
Sanudo, Carolina .
INORGANICA CHIMICA ACTA, 2011, 373 (01) :73-78
[9]   Thiocyanate and Dicyanamide Anion Controlled Nuclearity in Mn, Co, Ni, Cu, and Zn Metal Complexes with Hemilabile Ligand 2-Benzoylpyridine [J].
Ghosh, Totan ;
Chattopadhyay, Tanmay ;
Das, Sudhanshu ;
Mondal, Sandip ;
Suresh, Eringathodi ;
Zangrando, Ennio ;
Dast, Debasis .
CRYSTAL GROWTH & DESIGN, 2011, 11 (07) :3198-3205
[10]   C3-symmetric trinuclear copper(II) species as tectons in crystal engineering [J].
Ion, Adrian E. ;
Nica, Simona ;
Madalan, Augustin M. ;
Lloret, Francesc ;
Julve, Miguel ;
Andruh, Marius .
CRYSTENGCOMM, 2013, 15 (02) :294-301