ORGANOMETALLIC NITROSYL CHEMISTRY .9. (ETA-C5H5)W(NO)(ETA-3-C3H5)I, A CHIRAL ORGANOMETALLIC COMPLEX CONTAINING A VERY ASYMMETRIC ALLYL LIGAND

被引：39

作者：

GREENHOUGH, TJ ^{[1
]}

LEGZDINS, P ^{[1
]}

MARTIN, DT ^{[1
]}

TROTTER, J ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1W5,BC,CANADA

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 11期

关键词：

D O I：

10.1021/ic50201a064

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the explanation of the remarkable stereoselectivity observed during reactions of CpMo(CO)(NO)(η3-allyl)+ [Cp = η5-C5H5] cations with nucleophiles, it has been suggested that electronic asymmetry of the metal atom in the cation probably distorts the allyl ligand so as to localize the π-electron density between the carbon atoms trans to NO.2 We now wish to report that just such a distortion occurs to a marked degree in the related chiral complex CpW(NO)(η3-C3H5)I, a feature which permits the straightforward assignment of its 1H and 13C NMR spectra. © 1979, American Chemical Society. All rights reserved.

引用

页码：3268 / 3270

页数：3

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