HOMOLOGATION OF CARBOXYLIC-ACIDS BY IMPROVED METHODS BASED ON RADICAL CHAIN CHEMISTRY OF ACYL DERIVATIVES OF N-HYDROXY-2-THIOPYRIDONE

被引：30
作者：
BARTON, DHR
CHERN, CY
JASZBERENYI, JC
机构：
[1] Department of Chemistry, Texas A and M University, College Station
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 35期
关键词：
D O I：
10.1016/S0040-4039(00)61176-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reaction of substituted terminal olefins with carbon radicals generated from carboxylic acids gives adducts that can be transformed to one carbon atom longer homo-acids in high overall yield. With 6b yields are very good and the conditions of hydrolysis exceptionally mild.
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页码：5013 / 5016
页数：4
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