CHARGE-TRANSFER TRANSITIONS OF "PENTACYANO-BENZONITRILE-FERRATE(II)

被引：6

作者：

CALZAFERRI, G

GRUNIGER, HR

机构：

[1] Institut Für Anorganische Und Physikalische Chemie, Universität Bern, Bern, CH-3012

来源：

HELVETICA CHIMICA ACTA | 1979年 / 62卷 / 04期

关键词：

D O I：

10.1002/hlca.19790620421

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Charge Transfer Transitions of Pentacyano‐Benzonitrile‐Ferrate(II) Pentacyano‐benzontrile‐ferrate(II) shows two charge transfer transitions, which are interpreted as central atom to benzonitrile transitions d‐1π* and d‐2π*. Selective excitation to the d‐1π* state leads to a completely reversible photoreaction. An isosbestic point is observed at 398 nm in aqueous solution. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：1112 / 1120

页数：9

共 25 条

[1]

Ballhausen C.J., 1965, MOL ORBITAL THEORY

[2]

Balzani V., 1970, PHOTOCHEMISTRY COORD

[3]

Beens H., 1975, Organic molecular photophysics. Vol.2, P159

[4]

CALZAFER.G, 1972, BERICH BUNSEN GESELL, V76, P1143