SOLVENT EFFECTS ON AN ENZYMATIC ESTER SYNTHESIS IN SUPERCRITICAL CARBON-DIOXIDE

被引：40

作者：

IKUSHIMA, Y

SAITO, N

YOKOYAMA, T

HATAKEDA, K

ITO, S

ARAI, M

BLANCH, HW

机构：

[1] TOHOKU UNIV, INST CHEM REACT SCI, SENDAI, MIYAGI 980, JAPAN

[2] UNIV CALIF BERKELEY, DEPT CHEM ENGN, BERKELEY, CA 94720 USA

来源：

CHEMISTRY LETTERS | 1993年 / 01期

关键词：

D O I：

10.1246/cl.1993.109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ester synthesis from oleic acid and (+/-)-citronellol by lipase was carried out in supercritical carbon dioxide(SC-CO2). In the near-critical region, the rate of reaction was considerably enhanced and (S)-(-)-oleic acid 3,7-dimethyl-6-octenyl ester was stereoselectively formed. The results were discussed with taking account of solvent properties of SC-CO2 and aggregation phenomenon about reacting species at high pressures.

引用

页码：109 / 112

页数：4

共 7 条

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