ELECTRICAL AND PHYSICAL-PROPERTIES OF NEW ELECTRICALLY CONDUCTING QUASI COMPOSITES - POLY(ANILINE-CO-N-BUTYLANILINE) COPOLYMERS

被引：67

作者：

BERGERON, JY ^{[1
]}

DAO, LH ^{[1
]}

机构：

[1] INST NATL RECH SCI,RECH MAT AVANCES LAB,CP 1020,VARENNES J3X 1S2,QUEBEC,CANADA

来源：

MACROMOLECULES | 1992年 / 25卷 / 13期

关键词：

D O I：

10.1021/ma00039a002

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of poly(aniline-co-N-butylaniline) copolymers has been chemically synthesized in 0.1 M perchloric acid with ammonium persulfate as oxidant. The composition of the resulting copolymere has been determined by H-1 NMR analysis. The electrical and physical properties of the copolymers were also investigated, and they were found to depend strongly on the actual composition. The poly(aniline-co-N-butylaniline) copolymers show a percolation transition in the conductivity for aniline contents higher than 15%. They are probably the first known example of a "quasi composite" where both conducting and insulating segments are located within the same macromolecule.

引用

页码：3332 / 3337

页数：6

共 40 条

[31] COPOLYMERS OF PYRROLE AND BITHIOPHENE BY OXIDATIVE ELECTROPOLYMERIZATION [J].

PETERS, EM ;

VANDYKE, JD .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1991, 29 (10) :1379-1385

[32] ELECTROCHEMICAL COPOLYMERIZATION OF PYRROLE WITH N-SUBSTITUTED PYRROLES - EFFECT OF COMPOSITION ON ELECTRICAL-CONDUCTIVITY [J].

REYNOLDS, JR ;

POROPATIC, PA ;

TOYOOKA, RL .

MACROMOLECULES, 1987, 20 (05) :958-961

[33]

ROTH S, 1989, MATER SCI FORUM, V42, P1

[34]

SATO M, 1990, MAKROMOL CHEM, V191, P313

[35]

SKOTHEIM T, 1987, HDB CONDUCTING POLYM, V1

[36] POLARON LATTICE IN HIGHLY CONDUCTING POLYANILINE - THEORETICAL AND OPTICAL STUDIES [J].

STAFSTROM, S ;

BREDAS, JL ;

EPSTEIN, AJ ;

WOO, HS ;

TANNER, DB ;

HUANG, WS ;

MACDIARMID, AG .

PHYSICAL REVIEW LETTERS, 1987, 59 (13) :1464-1467

[37] POLYANILINE - A MATERIAL STILL UNDER DISCUSSION [J].

TRAVERS, JP ;

GENOUD, F ;

MENARDO, C ;

NECHTSCHEIN, M .

SYNTHETIC METALS, 1990, 35 (1-2) :159-168

[38] ELECTROCHEMICAL POLYMERIZATION OF ANILINE AND N-ALKYLANILINES [J].

WATANABE, A ;

MORI, K ;

IWABUCHI, A ;

IWASAKI, Y ;

NAKAMURA, Y ;

ITO, O .

MACROMOLECULES, 1989, 22 (09) :3521-3525

[39] CHEMICAL AND ELECTROCHEMICAL COPOLYMERIZATION OF ANILINE WITH ALKYL RING-SUBSTITUTED ANILINES [J].

WEI, Y ;

HARIHARAN, R ;

PATEL, SA .

MACROMOLECULES, 1990, 23 (03) :758-764

[40] ELECTRONIC AND MAGNETIC CHARACTER OF ANILINE-THIOPHENE COPOLYMERS [J].

YOUNG, CL ;

POLIS, DW ;

BAIN, AN ;

SAPOCHAK, LS ;

DALTON, LR .

MACROMOLECULES, 1990, 23 (13) :3236-3242

← 1 2 3 4 →