ELECTRICAL AND PHYSICAL-PROPERTIES OF NEW ELECTRICALLY CONDUCTING QUASI COMPOSITES - POLY(ANILINE-CO-N-BUTYLANILINE) COPOLYMERS

被引：67

作者：

BERGERON, JY ^{[1
]}

DAO, LH ^{[1
]}

机构：

[1] INST NATL RECH SCI,RECH MAT AVANCES LAB,CP 1020,VARENNES J3X 1S2,QUEBEC,CANADA

来源：

MACROMOLECULES | 1992年 / 25卷 / 13期

关键词：

D O I：

10.1021/ma00039a002

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of poly(aniline-co-N-butylaniline) copolymers has been chemically synthesized in 0.1 M perchloric acid with ammonium persulfate as oxidant. The composition of the resulting copolymere has been determined by H-1 NMR analysis. The electrical and physical properties of the copolymers were also investigated, and they were found to depend strongly on the actual composition. The poly(aniline-co-N-butylaniline) copolymers show a percolation transition in the conductivity for aniline contents higher than 15%. They are probably the first known example of a "quasi composite" where both conducting and insulating segments are located within the same macromolecule.

引用

页码：3332 / 3337

页数：6

共 40 条

[21] A PROCESS LEADING TO THE DOMAIN-STRUCTURE OF ANILINE BLACK (POLYANILINE) [J].

LANGER, JJ .

SYNTHETIC METALS, 1990, 36 (01) :35-40

[22] N-SUBSTITUTED POLYANILINES .2. PHOTOACOUSTIC AND FT-IR SPECTRA OF POLY(N-METHYLANILINE) AND RELATED COPOLYMERS [J].

LANGER, JJ .

SYNTHETIC METALS, 1990, 35 (03) :301-305

[23]

LECLERC M, 1989, MACROMOLECULES, V22, P641

[24]

MANOHAR SK, 1989, SYNTHETIC MET, V29, pE349

[25]

MIZUMOTO M, 1989, SYNTHETIC MET, V28, pC639, DOI 10.1016/0379-6779(89)90584-5

[26]

NAKAJIMA T, 1989, SYNTHETIC MET, V28, pC629, DOI 10.1016/0379-6779(89)90583-3

[27] CHEMICAL COPOLYMERIZATION OF ANILINE WITH HALOGEN-SUBSTITUTED ANILINES [J].

NEOH, KG ;

KANG, ET ;

TAN, KL .

EUROPEAN POLYMER JOURNAL, 1990, 26 (04) :403-407

[28] POLY(N-BENZYLANILINE) (POLY(AMPS)/WO3 SOLID-STATE ELECTROCHROMIC CELL [J].

NGUYEN, MT ;

DAO, LH .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (07) :2131-2132

[29] DETERMINATION OF REACTIVITY RATIOS IN COPOLYMERIZATION [J].

ODRISCOLL, KF ;

REILLY, PM .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1987, 10 :355-374

[30]

PATINOLEAL H, 1980, J POLYM SCI POL LETT, V18, P219, DOI 10.1002/pol.1980.130180309

← 1 2 3 4 →