COMPLEXING PROCESSES ON THE IMMOBILIZED MATRICES OF HEXACYANOFERRATE(II) COPPER(II) AND NITROGEN-SULFUR-CONTAINING LIGANDS IN THIN GELATIN LAYER

被引：30

作者：

MIKHAILOV, OV

机构：

[1] Department of Inorganic Chemistry, Kazan Institute of Chemical Technology, Kazan

来源：

MONATSHEFTE FUR CHEMIE | 1991年 / 122卷 / 8-9期

关键词：

IMMOBILIZED MATRIX; COMPLEXING; THIN GELATIN LAYER;

D O I：

10.1007/BF00811458

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexing processes occurring between immobilized matrices obtained from Cu(II) hexacyanoferrates(II) and solutions of various nitrogen-sulfur-containing chelating ligands in thin gelatin layers have been studied. With Cu2[Fe(CN)6]-matrix, the complexing process is found to proceed according to pseudo-S(N)1-mechanism. The schemes of the processes in each of the above matrices are given. Examples of kinetic curves for particular systems ''hexacyanoferrate(II)copper(II)-ligand'' are presented.

引用

页码：595 / 603

页数：9

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