DIRECT CARBON-CARBON BOND FORMATION STRATEGY AT ALPHA-POSITION OF TERTIARY-AMINES BY PHOTOINDUCED ELECTRON-TRANSFER (PET) PROCESSES

被引：37

作者：

PANDEY, G

RANI, KS

LAKSHMAIAH, G

机构：

[1] Division of Organic Chemistry (Synthesis) National Chemical Laboratory, Pune

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)61203-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selectivity in PET reactions based on the differences in free energy (DELTA-G(et)) values for radical ion formation between amines (4-7) and allytrimethylsilane (2) is utilized for direct allylation at alpha-positions of 4-7 by insitu trapping of iminium cation by 2.

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收藏

页码：5107 / 5110

页数：4

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