THERMODYNAMIC PROPERTIES OF CADMIUM SELENIDE

被引：18

作者：

NASAR, A

SHAMSUDDIN, M

机构：

[1] Department of Metallurgical Engineering, Institute of Technology, Banaras Hindu University, Varanasi

来源：

JOURNAL OF THE LESS-COMMON METALS | 1990年 / 158卷 / 01期

关键词：

D O I：

10.1016/0022-5088(90)90439-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The free energy of formation of CdSe has been determined by an electrochemical technique using a molten salt electrolyte. From measurements of the open-circuit e.m.f. of the galvanic cell at different temperatures the following relationship for ΔGf0 vs. T has been established: ΔGf0 = -159403 + 36.14T J mol-1 (640 < T < 825 K) The enthalpy of formation has been measured in a differential thermal analysis (DTA) calorimeter. The entropy of formation has been obtained by combining these experimentally determined values. © 1990.

引用

页码：131 / 135

页数：5

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