3-Methyl-1,2,3,4,5,6,1',2',3',4'-decahydrospiro[benz[f]isoquinoline-1,2'naphthalen]-1'-one

被引：3

作者：

Siaka, Sohro ^{[1
]}

Soldatenkov, Anatoly T. ^{[2
]}

Malkova, Anastasia V. ^{[2
]}

Sorokina, Elena A. ^{[2
]}

Khrustalev, Victor N. ^{[3
]}

机构：

[1] Inst Natl Polytech Felix HOUPHOUET BOIGNY, BP 1093, Yamous Soukro, Cote Ivoire

[2] Peoples Friendship Univ Russia, Organ Chem Dept, Moscow 117198, Russia

[3] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, XRay Struct Ctr, Moscow 119991, Russia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 17.9; mean ̄(C-C) = 0.002 Å; R factor = 0.045; single-crystal X-ray study; T = 100 K; wR factor = 0.122;

D O I：

10.1107/S1600536812043309

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C23H23NO, is the product of a tandem transformation of the double Mannich base bis(1-oxo-1,2,3,4-tertrahydro-2-naphthoylmethyl) amine hydrochloride in HBr solution upon heating. The tetrahydropyridine ring has a nonsymmetrical half-chair conformation, whereas the cyclohexadiene and cyclohexene rings adopt non-symmetrical half-boat conformations. The dihedral angle between the planes of the terminal benzene rings is 62.85 (6)degrees. The N atom has a trigonal-pyramidal geometry [sum of the bond angles = 332.4 (3)degrees]. In the crystal, molecules form [001] chains via weak non-classical C-H center dot center dot center dot N hydrogen bonds. The chains are stacked along the b axis.

引用

页码：O3230 / +

页数：10

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