THE ADSORPTION OF ANIONIC NAPHTHALENE DERIVATIVES AT THE GRAPHITE AQUEOUS-SOLUTION INTERFACE

被引：33

作者：

KIM, BS ^{[1
]}

HAYES, RA ^{[1
]}

RALSTON, J ^{[1
]}

机构：

[1] UNIV S AUSTRALIA,SCH CHEM TECHNOL,ADELAIDE,SA 5095,AUSTRALIA

来源：

CARBON | 1995年 / 33卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

ADSORPTION; NAPHTHALENE DERIVATIVES; FUNCTIONAL GROUPS;

D O I：

10.1016/0008-6223(94)00101-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption behaviour of anionic naphthalene derivatives at the graphite-aqueous solution interface has been studied at 25 degrees C at pH 7 and an ionic strength of 0.05 M. The orientation and packing of the adsorbates is strongly dependent upon the number and type of functional groups attached to the aromatic rings. A thermodynamic analysis has been used to evaluate quantitatively the adsorbate-adsorbent and adsorbate-adsorbate interactions. These interactions are related to the chemical structure of the adsorbate anions.

引用

页码：25 / 34

页数：10

共 22 条

[1] BARDI U, 1986, SURF SCI, V165, pL7, DOI 10.1016/0039-6028(86)90656-4
[2] VAN DER WAALS VOLUMES + RADII
BONDI, A
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) : 441 - +
[3] ADSORPTION OF ETHOXYLATED SULFONATE AND NONIONIC HOMOLOGS ON COAL
CELIK, MS
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1989, 129 (02) : 428 - 440
[4] CHAPMAN DL, 1947, CHEM REV, V41, P444
[5] ADSORPTION OF TETRAALKYLAMMONIUM IONS AT THE SILVER IODIDE-ELECTROLYTE INTERFACE
DEKEIZER, A
LYKLEMA, J
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1980, 75 (01) : 171 - 184
[6] THERMODYNAMICS OF ADSORPTION FROM SOLUTION .2. IMPERFECT SYSTEMS
EVERETT, DH
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1965, 61 (515P): : 2478 - &
[7] FEWINGS JH, 1971, P AUS I MIN METALL, V237, P41
[8] THE GRAPHON POLYELECTROLYTES INTERFACE AS A MODEL FOR COAL SLURRIES
GABRIELLI, G
FERRONI, E
CAMINATI, G
ERCOLANI, D
[J]. COLLOIDS AND SURFACES, 1990, 48 (1-3): : 231 - 241
[9] Galbraith J. W, 1958, J APPL CHEM, V8, P416
[10] Hunter R.J., 1981, ZETA POTENTIAL COLLO, DOI [10.1016/c2013-0-07389-6, 10.1016/j.berh.2014.02.004]

← 1 2 3 →