[4,4',6,6'-TETRAMETHYL-(2,2'-ISOBUTYLIDENE-DI-O-PHENYLENE)] (2,6,7-TRIOXA-1-PHOSPHA-BICYCLO[2.2.2]OCT-4-YLMETHYL) PHOSPHITE, C25H32P2O6

被引：2

作者：

ELNAGAR, HY ^{[1
]}

LAYMAN, WJ ^{[1
]}

FRONCZEK, FR ^{[1
]}

机构：

[1] LOUISIANA STATE UNIV,DEPT CHEM,BATON ROUGE,LA 70803

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194011169

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The eight-membered ring in the diphosphite exists in a boat-chair conformation in which the electron lone pair Germain, on the P atom and the bridged methine have an anti relationship. The sterically more demanding isopropyl group is disposed away from the cage phosphite moiety. The endocyclic bond angle at the C atom bearing the isopropyl group is 111.2(2)degrees.

引用

页码：1177 / 1179

页数：3