SYNTHESES AND PROPERTIES OF FERROCENYLETHYNYL TRANSITION-METAL COMPLEXES OF PLATINUM, PALLADIUM, AND NICKEL

被引：11
|
作者：
ONITSUKA, K [1 ]
TAO, XQ [1 ]
SONOGASHIRA, K [1 ]
机构：
[1] OSAKA CITY UNIV, FAC ENGN, DEPT APPL CHEM, SUMIYOSHI KU, OSAKA 558, JAPAN
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 09期
关键词：
D O I：
10.1246/bcsj.67.2611
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Square planar ferrocenylethynyl transition metal complexes M(C=CFc)2(PR3)2 (M = Pt, Pd, Ni; Fc = (C5H4)Fe(C5H5)) were prepared by the reaction of MCl2(PR3)2 with ethynylferrocene in the presence of a CuI catalyst in diethylamine, and characterized by spectral analyses. An interaction between transition metals and an iron atom was studied by using electronic spectroscopy.
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页码：2611 / 2613
页数：3
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