A HIGHLY-ACTIVE SOLID SUPERACID CATALYST FOR N-BUTANE ISOMERIZATION - A SULFATED OXIDE CONTAINING IRON, MANGANESE AND ZIRCONIUM

被引：287

作者：

HSU, CY ^{[1
]}

HEIMBUCH, CR ^{[1
]}

ARMES, CT ^{[1
]}

GATES, BC ^{[1
]}

机构：

[1] UNIV DELAWARE,CTR CATALYT SCI & TECHNOL,DEPT CHEM ENGN,NEWARK,DE 19716

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 22期

关键词：

D O I：

10.1039/c39920001645

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A porous sulfated metal oxide containing Fe, Mn and Zr is described; it is the most active nonhalide superacid catalyst yet reported, catalysing the isomerization of n-butane at 301 K and being about three orders of magnitude more active than sulfated ZrO2.

引用

页码：1645 / 1646

页数：2

共 14 条

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[9] DETECTION OF SUPERACIDITY ON SOLID SUPERACIDS - A NEW APPROACH
LIN, CH
HSU, CY
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (20) : 1479 - 1480
[10] Olah G. A., 1985, SUPERACIDS

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