Deactivation of Molybdenum Scrap from Uranium Dioxide Production and Developing a Fluoride Technology for Its Processing

被引:0
作者
Makarov, F. V. [1 ]
Guzeev, V. V. [1 ]
Pishchulin, V. P. [1 ]
Svarovskaya, A. Ya. [1 ]
Guzeeva, T. I. [2 ]
机构
[1] Natl Res Nucl Univ MEPhl, Branch State Budget Educ Inst Higher Profess Educ, Seversk Technol Inst, Pr Kommunisticheskiy 65, Seversk 636036, Tomskaya Obl, Russia
[2] Tomsk Polytech Univ, Tomsk 634050, Russia
来源
CHEMISTRY FOR SUSTAINABLE DEVELOPMENT | 2011年 / 19卷 / 04期
关键词
molybdenum; uranium dioxide; waste; fluorination; kinetics; deactivation;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Deactivation and processing of the man-caused wastes of molybdenum from the production of uranium dioxide by means of fluorination with elemental fluorine were studied. The level and depth of molybdenum contamination with radioactive substances were established, the major physicochemical parameters of molybdenum fluorination were determined: the equilibrium composition, duration and conditions of reaction. The apparent activation energies were determined, and kinetic equations were deduced.
引用
收藏
页码:347 / 353
页数:7
相关论文
共 11 条
[1]  
Andreev G. G., 2004, IZV VUZ FIZ, V47, P219
[2]  
Bol'shakov K.A., 1976, KHIMIYA TEKHNOLOGIYA
[3]  
Khabashi F., 1974, OSNOVY PRIKLADNOY ME, V1
[4]  
Korolev Yu. M., 1981, VOSSTANOVLENIYE FTOR, P7
[5]  
Kutepov A. M., 1990, OBSHCHAYA KHIMICHESK
[6]  
Makarov F. V., 2005, THESIS, P74
[7]  
Makarov F. V., 2008, TSV METALLY, V6, P78
[8]  
Opalovskiy A. A., 1972, GALOGENIDY MOLIBDEN
[9]  
Osin S. B., 1998, 10 S KHIM NEORG FTOR, P121
[10]  
Yagodin G. A., 1977, MENDELEEV U CHEM TEC, P3