THE STRUCTURE OF COPPER(II) 5,7,12,14-TETRAMETHYLDIBENZO[B,I][1,4,8,11]-TETRAAZACYCLOTETRADECA-2,4,7,9,11,14-HEXAENEDIIDE

被引：8

作者：

COTTON, FA ^{[1
]}

CZUCHAJOWSKAWIESINGER, J ^{[1
]}

机构：

[1] TEXAS A&M UNIV SYST,MOLEC STRUCT & BONDING LAB,COLL STN,TX 77843

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270192000726

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[CU(C22H22N4)], M(r) = 405.99, monoclinic, P2(1)/c, a = 14.318 (2), b = 16.427 (2), c = 16.299 (2) angstrom, beta = 100.01 (1)-degrees, V = 3775 (1) angstrom3, Z = 8, D(x) = 1.429 g CM-3, lambda(Cu K-alpha) = 1.54183 angstrom, mu = 16.88 cm-1, F(000) = 1688, T = 296 K, R = 0.0355, 4237 unique observations with I > 3-sigma(I). There are two crystallographically independent molecules but they are virtually identical. Each has the ligand, tmtaa, in a flattened saddle conformation, whereby the Cu ion can have nearly planar coordination. The Cu-N distances range from 1.922 (2) to 1.948 (2) angstrom with a mean value of 1.930 angstrom.

引用

页码：1434 / 1437

页数：4

共 13 条

[1]

[Anonymous], 1986, SHELXS86 PROGRAM SOL

[2] CRYSTAL STRUCTURE OF BETA-COPPER PHTHALOCYANINE [J].

BROWN, CJ .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (10) :2488-&

[3] DIBENZO[B,I][1,4,8,11]TETRA-AZACYCLOTETRADECINE COMPLEXES .2. RU(TMTAA)(PMEPH2)2 [J].

COTTON, FA ;

CZUCHAJOWSKA, J .

POLYHEDRON, 1990, 9 (09) :1221-1224

[4]

COTTON FA, 1990, POLYHEDRON, V9, P2533

[5]

GOEDKIN VL, 1976, J AM CHEM SOC, V38, P8014

[6] AMINOMETHYLENE-BETA-DICARBONYL COMPOUNDS AS COMPLEX-FORMING LIGANDS .5. NEW UNSATURATED-CONJUGATED NEUTRAL COMPLEXES WITH 14-MEMBERED MACROCYCLIC LIGANDS [J].

JAGER, EG .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1969, 364 (3-4) :177-&

[7]

JOHNSON CK, 1965, ORNL3794 REP

[8] A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].

NORTH, ACT ;

PHILLIPS, DC ;

MATHEWS, FS .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&

[9] REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES [J].

SHANNON, RD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (SEP1) :751-767

[10] PALLADIUM TETRAAZAANNULENES - SYNTHESIS AND STRUCTURE OF PALLADIUM 5,7,12,14-TETRAMETHYLDIBENZO[B,I][1,4,8,11]TETRAAZA[14]ANNULENE [J].

TSUTSUI, M ;

BOBSEIN, RL ;

CASH, G ;

PETTERSEN, R .

INORGANIC CHEMISTRY, 1979, 18 (03) :758-761

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