CYCLIZATIONS AND INTERMOLECULAR ADDITIONS OF ALKOXYCARBONYLOXY RADICALS FROM N-HYDROXYPYRIDINE-2-THIONE CARBONATES

被引：45
作者：
NEWCOMB, M
KUMAR, MU
BOIVIN, J
CREPON, E
ZARD, SZ
机构：
[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLLEGE STN,TX 77843
[2] ECOLE POLYTECH,SYNTH ORGAN LAB,F-91123 PALAISEAU,FRANCE
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 01期
关键词：
D O I：
10.1016/S0040-4039(00)71214-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Alkoxycarbonyloxy radicals from allyl and homoallyl alcohols cyclize in an exo fashion to give, respectively, 3-substituted 1,2-diol carbonates and 4-substituted 1,3-diol carbonates whereas simple alkoxycarbonyloxy radicals add intermolecularly to ethyl vinyl ether to give, ultimately, carbonates of glycolaldehyde derivatives.
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页码：45 / 48
页数：4
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