STRUCTURE OF ACRIDINIUM TRANS-TETRACHLOROBIS(DIMETHYL SULFOXIDE)RUTHENATE(III)

被引：16

作者：

CALLIGARIS, M

BRESCIANIPAHOR, N

SRIVASTAVA, RS

机构：

[1] Dipartimento Eli Scienze Chimiche, Universitd di Trieste, Trieste

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S010827019200725X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acridinium (OC-6-11)-Tetrachlorobis(dimethyl sulfoxide)ruthenate(III), [C13H10N][RuCl4-(C2H6OS)2], M(r) = 579.38, monoclinic, P2(1)/c, a = 10.536 (1), b = 13.372 (1), c = 16.619 (1) angstrom, beta = 102.25 (1)-degrees, V = 2288.1 (3) angstrom3, Z = 4, D(x) = 1.682 g cm-3, lambda(Mo Kalpha) = 0.71073 angstrom, mu = 13.3 cm-1, F(000) = 11 64, T = 294 K, R = 0.03 1, wR = 0.038 for 4321 unique observed reflections. The structure of the anion is characterized by a trans arrangement of the two sulfur-bonded dimethyl sulfoxide ligands. Average bond distances are Ru-Cl 2.349 (8) and Ru-S 2.35 (1) angstrom.

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页码：448 / 451

页数：4

相关论文

共 16 条

[1] SYNTHESIS, MOLECULAR-STRUCTURE, AND CHEMICAL BEHAVIOR OF HYDROGEN TRANS-BIS(DIMETHYL SULFOXIDE)TETRACHLORORUTHENATE(III) AND MER-TRICHLOROTRIS(DIMETHYL SULFOXIDE)RUTHENIUM(III) - THE 1ST FULLY CHARACTERIZED CHLORIDE DIMETHYL-SULFOXIDE RUTHENIUM(III) COMPLEXES [J].

ALESSIO, E ;

BALDUCCI, G ;

CALLIGARIS, M ;

COSTA, G ;

ATTIA, WM ;

MESTRONI, G .

INORGANIC CHEMISTRY, 1991, 30 (04) :609-618

[2] SYNTHESIS AND CHARACTERIZATION OF NEW HALOGEN TETRAMETHYLENE SULFOXIDE-RUTHENIUM(II) AND RUTHENIUM(III) COMPLEXES - CRYSTAL-STRUCTURE OF CIS-DICHLOROTETRAKIS(TETRAMETHYLENE SULFOXIDE)RUTHENIUM(II) AND HYDROGEN TRANS-BIS(TETRAMETHYLENE SULFOXIDE)TETRACHLORORUTHENATE(III) [J].

ALESSIO, E ;

MILANI, B ;

MESTRONI, G ;

CALLIGARIS, M ;

FALESCHINI, P ;

ATTIA, WM .

INORGANICA CHIMICA ACTA, 1990, 177 (02) :255-265

[3] CIS-DIHALOTETRAKIS(DIMETHYL SULFOXIDE)RUTHENIUM(II) AND TRANS-DIHALOTETRAKIS(DIMETHYL SULFOXIDE)RUTHENIUM(II) COMPLEXES (RUX2(DMSO)4, X = CL, BR) - SYNTHESIS, STRUCTURE, AND ANTITUMOR-ACTIVITY [J].

ALESSIO, E ;

MESTRONI, G ;

NARDIN, G ;

ATTIA, WM ;

CALLIGARIS, M ;

SAVA, G ;

ZORZET, S .

INORGANIC CHEMISTRY, 1988, 27 (23) :4099-4106

[4] RUTHENIUM(II) CHLORIDE COMPLEXES OF THE MESOCYCLIC LIGAND 1,5-DITHIACYCLOOCTANE 1-OXIDE - PREPARATION AND STRUCTURE OF THE ALL-TRANS COMPLEX [J].

ARBUCKLE, BW ;

BHARADWAJ, PK ;

MUSKER, WK .

INORGANIC CHEMISTRY, 1991, 30 (03) :440-445

[5]

Davis J. A., 1981, ADV INORG CHEM, V24, P115

[6] RUTHENIUM(II)-DIMETHYL SULFOXIDE COMPLEXES WITH NITROGEN LIGANDS - SYNTHESIS, CHARACTERIZATION AND SOLUTION CHEMISTRY - THE CRYSTAL-STRUCTURES OF CIS,FAC-RUCL2(DMSO)3(NH3) AND TRANS,CIS,CIS-RUCL2(DMSO)2(NH3)2.H2O [J].

HENN, M ;

ALESSIO, E ;

MESTRONI, G ;

CALLIGARIS, M ;

ATTIA, WM .

INORGANICA CHIMICA ACTA, 1991, 187 (01) :39-50

[7] RUTHENIUM(III) COMPLEXES CONTAINING DIMETHYLSULFOXIDE OR DIMETHYLSULFIDE LIGANDS, AND A NEW ROUTE TO TRANS-DICHLOROTETRAKIS(DIMETHYLSULFOXIDE)RUTHENIUM(II) [J].

JASWAL, JS ;

RETTIG, SJ ;

JAMES, BR .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1990, 68 (10) :1808-1817

[8]

JOHNSON CK, 1976, ORNL5138 REP

[9] SYNTHESIS, MOLECULAR-STRUCTURE, AND TUMOR-INHIBITING PROPERTIES OF IMIDAZOLIUM TRANS-BIS(IMIDAZOLE)TETRACHLORORUTHENATE(III) AND ITS METHYL-SUBSTITUTED DERIVATIVES [J].

KEPPLER, BK ;

RUPP, W ;

JUHL, UM ;

ENDRES, H ;

NIEBL, R ;

BALZER, W .

INORGANIC CHEMISTRY, 1987, 26 (26) :4366-4370

[10] SYNTHESIS, ANTITUMOR-ACTIVITY, AND X-RAY STRUCTURE OF BIS(IMIDAZOLIUM)(IMIDAZOLE)PENTACHLORORUTHENATE(III), (IMH)2(RUIMCL5) [J].

KEPPLER, BK ;

WEHE, D ;

ENDRES, H ;

RUPP, W .

INORGANIC CHEMISTRY, 1987, 26 (06) :844-846