TEMPLATE-CONTROLLED OLIGOMERIZATION SUPPORT STUDIES - TEMPLATE SYNTHESIS AND FUNCTIONALIZATION

被引：26
作者：
FELDMAN, KS
BOBO, JS
ENSEL, SM
LEE, YB
WEINREB, PH
机构：
[1] Department of Chemistry, The Pennsylvania State University, University Park
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 02期
关键词：
D O I：
10.1021/jo00289a019
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The rigid organic template 8 can be rapidly assembled via double Diels-Alder cycloaddition of methyl 9-anthracenecarboxylate (7) and trams-anti-trans-norbornadiene trimer 5. Subsequent manipulation leads to differentially functionalized templates capable of mediating the oligoselective polymerization of acrylate monomers. Lactonization studies with template diol 10 provide a useful measure of the “effective molecular size” of the template. © 1990, American Chemical Society. All rights reserved.
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页码：474 / 481
页数：8
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