HYDROXYLAMMONIUM NITRATE AS GREEN PROPELLANT: DECOMPOSITION AND STABILITY

被引：18

作者：

Amrousse, R. ^{[1
]}

Katsumi, T. ^{[1
]}

Sulaiman, T. ^{[1
]}

Das, B. R. ^{[1
]}

Kumagai, H. ^{[2
]}

Maeda, K. ^{[2
,3
]}

Hori, K. ^{[1
]}

机构：

[1] Japan Aerosp Explorat Agcy, JAXA, Chuo Ku, 3-1-1 Yoshinodai, Sagamihara, Kanagawa 2525210, Japan

[2] Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan

[3] Japan Sci & Technol Agcy, Precursory Res Embryon Sci & Technol, Saitama 3320012, Japan

来源：

INTERNATIONAL JOURNAL OF ENERGETIC MATERIALS AND CHEMICAL PROPULSION | 2012年 / 11卷 / 03期

关键词：

HAN aqueous mixtures; fuels; thermal and catalytic decomposition;

D O I：

10.1615/IntJEnergeticMaterialsChemProp.2012004978

中图分类号：

V [航空、航天];

学科分类号：

08 ; 0825 ;

摘要：

Binary hydroxyl ammonium nitrate (HAN) aqueous mixtures have been prepared. Four series of ternary mixtures have been synthesized with methanol and ethanol as fuels: two series with HAN excess and two other series with stoichiometric fuel contents. Thermal and catalytic decomposition of the prepared solutions have been analyzed. For binary HAN solutions, the thermal decomposition starts only once water has been fully vaporized and the oxidizer is in the liquid state. The influence of the fuel depends strongly on the oxidizer. Methanol and ethanol are vaporized before the decomposition, leading to results close to those observed for binary mixtures. HAN and HAN-fuel-based solutions display the highest catalytic effect with a temperature decrease of about 100 degrees C.

引用

页码：241 / 257

页数：17

共 9 条

[1]

Amrousse R., 2010, P 2 2 46 JOINT PROP, P6983

[2] Facile catalytic decomposition at low temperature of energetic ionic liquid as hydrazine substitute [J].