STRONG RHODIUM-NIOBIA INTERACTION ON SILICA SURFACE FORMED BY HIGH-TEMPERATURE CALCINATION TREATMENT

被引:13
作者
Hu, Z. [1 ]
Nakamura, H. [1 ]
Kunimori, K. [1 ]
Uchijima, T. [1 ]
机构
[1] Univ Tsukuba, Inst Mat Sci, Tsukuba, Ibaraki 305, Japan
关键词
D O I
10.1007/BF00765306
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Air calcination of a Rh-Nb2O5/SiO2 catalyst (Nb : Rh =1 :1) at high temperature (900 degrees C) produced a single phase of RhNbO4 detected by X-ray diffraction. This catalyst system, followed by high-temperature reduction at 500 degrees C, was found to exhibit a strong metal-support interaction behavior from H-2 or CO chemisorption and ethane hydrogenolysis studies.
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页码:271 / 274
页数:4
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