THE GENERATION OF CARBONYL-COMPOUNDS FROM ACETALS AND KETALS BY IODOTRICHLOROSILANE (ITCS)

被引：18

作者：

ELMORSY, SS

BHATT, MV

PELTER, A

机构：

[1] INDIAN INST SCI,DEPT ORGAN CHEM,BANGALORE 560012,KARNATAKA,INDIA

[2] UNIV COLL SWANSEA,DEPT CHEM,SWANSEA SA2 8PP,W GLAM,WALES

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 12期

关键词：

D O I：

10.1016/S0040-4039(00)91700-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cheap and readily available iodotrichlorosilane (SiCl4/ NaI) readily regenerates aldehydes and ketones from cyclic and acyclic acetals and ketals, in 20-60 min at ambient temperature. The reaction is highly chemoselective as phenolic ethers and esters are not cleaved. The pathway for the process is unlike any previously proposed.

引用

页码：1657 / 1660

页数：4

共 26 条

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