Crystal structure of bis[2-(benzothiazol-2-yl)phenolato-kappa N-2,O]copper(II)

被引：1

作者：

Kim, Namhun ^{[1
]}

Kang, Sung Kwon ^{[1
]}

机构：

[1] Chungnam Natl Univ, Dept Chem, Daejeon 305764, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; Cu(II) complex; benzothiazolphenol; hydrogen bonding; pi-pi interactions;

D O I：

10.1107/S2056989015015303

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Cu(C13H8NOS)(2)], the Cu-II atom is coordinated by two N atoms and two O atoms from two bidentate benzothiazolphenolate ligands, forming a distorted tetrahedral geometry [dihedral angle between two N-Cu-O planes: 45.1 (2)degrees]. The dihedral angles between the benzothiazole ring systems and the phenol rings are 4.1 (4) and 5.8 (4)degrees, indicating an almost planar geometry. Weak intraand intermolecular C-H center dot center dot center dot O hydrogen bonds are observed. In the crystal, weak pi-pi interactions between aromatic and thiazole rings [centroid- centroid distances = 3.626 (3) and 3.873 (3) angstrom] link the molecules into a two-dimensional supramolecular network along the bc plane.

引用

页码：M173 / +

页数：11

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