OXIDATION OF PROPYLENE TO ACRYLIC-ACID AND ITS ESTERS CATALYZED BY PALLADIUM GIANT CLUSTERS

被引：0
|
作者：
PASICHNYK, PI
STARCHEVSKY, MK
PAZDERSKY, YA
ZAGORODNIKOV, VP
VARGAFTIK, MN
MOISEEV, II
机构：
[1] NS KURNAKOV GEN & INORGAN CHEM INST,117907 MOSCOW,RUSSIA
[2] SYNTEZ RES INST,293760 BORISLAV,UKRAINE
[3] ND ZELINSKII INST ORGAN CHEM,117913 MOSCOW,RUSSIA
来源：
MENDELEEV COMMUNICATIONS | 1994年 / 01期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Propylene has been catalytically oxidized by dioxygen to acrylic acid and/or its esters in high yield (60-80%) in acidified aqueous and/or alcoholic solutions of palladium-561 giant clusters, whereas ethylene has been converted to acetic acid; this is the first example of acid-promoted palladium catalysis of alkene oxidation.
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页码：1 / 2
页数：2
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