DISTRIBUTION OF HALOGENATED PHENOLS INCLUDING MIXED BROMINATED AND CHLORINATED PHENOLS IN MUNICIPAL WASTE INCINERATION FLUE-GAS

被引：25

作者：

HEEB, NV

DOLEZAL, IS

BUHRER, T

MATTREL, P

WOLFENSBERGER, M

机构：

[1] Swiss Federal Laboratories for Materials Testing and Research

来源：

CHEMOSPHERE | 1995年 / 31卷 / 04期

关键词：

HALOGENATED PHENOLS; CHLORINATED PHENOLS; BROMINATED PHENOLS; MIXED BROMINATED AND CHLORINATED PHENOLS; MUNICIPAL WASTE INCINERATION; FLUE GAS; RAW GAS; STACK GAS;

D O I：

10.1016/0045-6535(95)00164-4

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Incineration of municipal waste yields a variety of halogenated phenols including chlorinated, brominated and mixed brominated and chlorinated phenols in raw and stack gas. A total of 14 chlorinated, 3 brominated and 31 mixed brominated and chlorinated phenols could be characterized by high resolution gas chromatography high resolution mass spectrometry (HRGC-HRMS). A significant molar fraction of halogenated phenols in raw and stack gas was found to be monobrominated (12% and 8%) and dibrominated (2% and 1%). The monitored fraction of polyhalogenated phenols can be characterized with an elemental composition of C6H2.6Br0.2Cl3.2O in raw and C6H2.5Br0.1Cl3.4O in stack gas.

引用

页码：3033 / 3041

页数：9

共 22 条

[1] REACTION PATHWAYS FOR THE FORMATION OF POLYCHLORO-DIBENZODIOXINS (PCDD) AND POLYCHLORO-DIBENZOFURANS (PCDF) IN COMBUSTION PROCESSES .2. CHLOROBENZENES AND CHLOROPHENOLS AS PRECURSORS IN THE FORMATION OF POLYCHLORO-DIBENZODIOXINS AND POLYCHLORO-DIBENZOFURANS IN FLAME CHEMISTRY [J].