Dibromido(4,4 '-dimethyl-2,2 '-bipyridine-kappa N-2,N')(dimethyl sulfoxide-kappa O)-cadmium

被引：6
作者：
Shirvan, Sadif A. [1 ]
Dezfuli, Sara Haydari [1 ]
机构：
[1] Islamic Azad Univ, Omidieh Branch, Dept Chem, Omidieh, Iran
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S1600536812028553
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [CdBr2(C12H12N2)(C2H6OS)], the Cd-II atom is five-coordinated in a distorted trigonal-bipyramidal geometry by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine (DMBP) ligand, one O atom from a dimethyl sulfoxide (DMSO) ligand and two Br atoms. A weak intramolecular C-H center dot center dot center dot O hydrogen bond occurs between the DMBP and DMSO ligands. pi-pi stacking between pyridine rings [centroid-centroid distances = 3.682 (3) and 3.598 (3) angstrom] is observed in the crystal.
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页码：M1006 / +
页数：9
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