(H2O)2 - SPECTROSCOPY, STRUCTURE AND DYNAMICS

被引：131
作者：
FRASER, GT
机构：
[1] Molecular Physics Division, National Institute of Standards and Technology, Gaithersburg, MD
来源：
INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY | 1991年 / 10卷 / 02期
关键词：
D O I：
10.1080/01442359109353257
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Tunnelling in water dimer allows each of the hydrogen atoms to participate in the hydrogen bonding, giving rise to a complicated energy-level scheme and rotational spectrum. As a result of new theoretical and experimental developments, great progress has been made in the analysis and interpretation of this spectrum, yielding detailed information about this hydrogen-bonded interaction. This paper reviews the spectroscopy of this highly non-rigid dimer, which is becoming a prototype systems for the study of multidimensional tunnelling problems in weakly bound complexes.
引用
收藏
页码：189 / 206
页数：18
相关论文
共 57 条
[1]   FOURIER-TRANSFORM AND CARS SPECTROSCOPY OF THE V1 AND V3 FUNDAMENTAL BANDS OF (NH3)-N-14 [J].
ANGSTL, R ;
FINSTERHOLZL, H ;
FRUNDER, H ;
ILLIG, D ;
PAPOUSEK, D ;
PRACNA, P ;
RAO, KN ;
SCHROTTER, HW ;
URBAN, S .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1985, 114 (02) :454-472
[2]   FABRY-PEROT CAVITY PULSED FOURIER-TRANSFORM MICROWAVE SPECTROMETER WITH A PULSED NOZZLE PARTICLE SOURCE [J].
BALLE, TJ ;
FLYGARE, WH .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1981, 52 (01) :33-45
[3]   AN INTERMOLECULAR POTENTIAL-ENERGY SURFACE FOR (HF)2 [J].
BARTON, AE ;
HOWARD, BJ .
FARADAY DISCUSSIONS, 1982, 73 :45-62
[4]   ROTATIONAL ANALYSIS OF THE 1B2U(PI-PI-STAR) ]-1A1G(610) BAND OF BENZENE AND HELIUM-BENZENE VANDERWAALS COMPLEXES IN A SUPERSONIC JET [J].
BECK, SM ;
LIVERMAN, MG ;
MONTS, DL ;
SMALLEY, RE .
JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (01) :232-237
[5]   TUNABLE FAR-INFRARED LASER SPECTROSCOPY OF HYDROGEN-BONDS - THE KA=O(U)-]1(G) ROTATION-TUNNELING SPECTRUM OF THE HCL DIMER [J].
BLAKE, GA ;
BUSAROW, KL ;
COHEN, RC ;
LAUGHLIN, KB ;
LEE, YT ;
SAYKALLY, RJ .
JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (11) :6577-6587
[6]  
BLAKE GA, 1989, J CHEM PHYS, V91, P4418
[7]   AN ABINITIO SEMIRIGID BENDER CALCULATION OF THE ROTATION AND TRANS-TUNNELING SPECTRA OF (HF)2 AND (DF)2 [J].
BUNKER, PR ;
CARRINGTON, T ;
GOMEZ, PC ;
MARSHALL, MD ;
KOFRANEK, M ;
LISCHKA, H ;
KARPFEN, A .
JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (09) :5154-5159
[8]   MEASUREMENT OF THE PERPENDICULAR ROTATION-TUNNELING SPECTRUM OF THE WATER DIMER BY TUNABLE FAR INFRARED-LASER SPECTROSCOPY IN A PLANAR SUPERSONIC JET [J].
BUSAROW, KL ;
COHEN, RC ;
BLAKE, GA ;
LAUGHLIN, KB ;
LEE, YT ;
SAYKALLY, RJ .
JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (08) :3937-3943
[9]   DETERMINATION OF THE BOUND AND QUASI-BOUND STATES OF AR-HCL VANDERWAALS COMPLEX - DISCRETE VARIABLE REPRESENTATION METHOD [J].
CHOI, SE ;
LIGHT, JC .
JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (04) :2129-2145
[10]   THE INFRARED PREDISSOCIATION SPECTRA OF WATER CLUSTERS [J].
COKER, DF ;
MILLER, RE ;
WATTS, RO .
JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (08) :3554-3562
123456