EFFECT OF STEPWISE AND CONTINUOUS REDUCTION IN IMPELLER SPEED ON PARTICLE-SIZE DISTRIBUTIONS IN SUSPENSION POLYMERIZATION OF STYRENE

被引：2

作者：

TANAKA, M ^{[1
]}

TANAKA, H ^{[1
]}

KIMURA, I ^{[1
]}

SAITO, N ^{[1
]}

HOSOGAI, K ^{[1
]}

机构：

[1] NAGAOKA COLL TECHNOL,NAGAOKA,NIIGATA 940,JAPAN

来源：

KAGAKU KOGAKU RONBUNSHU | 1995年 / 21卷 / 01期

关键词：

MIXING; SUSPENSION POLYMERIZATION; PARTICLE SIZE DISTRIBUTION; POLYSTYRENE PARTICLE; COALESCENCE;

D O I：

10.1252/kakoronbunshu.21.118

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Suspension polymerization of styrene was performed using calcium tertiary phosphate as the suspension stabilizer and sodium dodecylbenzenesulfonate as the suspension co-stabilizer. It was investigated how the stepwise and continuous reduction in impeller speed over the course of polymerization affected the final particle size distribution. Transient mean droplet diameters, final particle size distributions and final mean particle sizes were significantly affected by the degree of impeller speed reduction and the polymerization conversion. Three step reduction in the range of conversion from 0 to 0.45 was found to produce polymer particles of the most uniform size.

引用

页码：118 / 125

页数：8

共 5 条

[1]

HIROSE M, 1970, KAGAKU KOGAKU, V34, P181

[2] THE EFFECT OF STABILIZER ON COALESCENCE OF DISPERSED DROPS IN SUSPENSION POLYMERIZATION OF STYRENE [J].