THE PROPERTIES OF ORGANIC LIQUIDS THAT ARE RELEVANT TO THEIR USE AS SOLVATING SOLVENTS

被引：1402

作者：

MARCUS, Y

机构：

来源：

CHEMICAL SOCIETY REVIEWS | 1993年 / 22卷 / 06期

关键词：

D O I：

10.1039/cs9932200409

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solvation properties of solvents (solvent effects) depend mainly on their polarity/polarizability (accounting also for dispersion interactions), hydrogen bond donation and acceptance abilities, and cohesive energy density, that are orthogonal to each other. These are best measured by the Kamlet-Taft solvatochromic parameters pi*, alpha, and beta and the square of Hildebrand's solubility parameter, delta(H)2, respectively. The first three are presented for a large set of solvents, together with several other solvation indices that are correlated with them.

引用

页码：409 / 416

页数：8

共 36 条

[11] LINEAR SOLVATION ENERGY RELATIONSHIPS .23. A COMPREHENSIVE COLLECTION OF THE SOLVATOCHROMIC PARAMETERS, PI-STAR, ALPHA AND BETA, AND SOME METHODS FOR SIMPLIFYING THE GENERALIZED SOLVATOCHROMIC EQUATION [J].