FOOTPRINT CATALYSIS .6. CHIRAL MOLECULAR FOOTPRINT CATALYTIC CAVITIES IMPRINTED BY A CHIRAL TEMPLATE, BIS(N-BENZYLOXYCARBONYL-L-ALANYL)AMINE, AND THEIR STEREOSELECTIVE CATALYSES

Chiral ''molecular footprint'' catalytic cavities were formed on a silica(alumina) gel surface by molecular imprinting with a chiral template, bis(N-benzyloxycaxbonyl-L-alanyl)amine. These cavities exhibited stereoselective catalyses in the transacylation of the corresponding substrates: L-, D-, and meso- forms of bis(benzyloxycaxbonyl-alanyl) oxide.