METHYL DITHIOCARBAMATE GOLD(I) AND GOLD(III) COMPLEXES - SYNTHESIS AND REACTIVITY WITH AMINES

被引：16

作者：

BARDAJI, M ^{[1
]}

LAGUNA, A ^{[1
]}

LAGUNA, M ^{[1
]}

MERCHAN, F ^{[1
]}

机构：

[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN,E-50009 ZARAGOZA,SPAIN

来源：

INORGANICA CHIMICA ACTA | 1994年 / 215卷 / 1-2期

关键词：

GOLD COMPLEXES; DITHIOCARBAMATE COMPLEXES;

D O I：

10.1016/0020-1693(93)03688-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of several methyl dithiocarbamates {S(MeS)CNHR} (R=p-MeC(6)H(4), o-MeC(6)H(4), p-MeOC(6)H(4) and 3,5-Me(2)C(6)H(3)) with Au(C6F5)(tht) and Au(C6F5)(3)(OEt(2)) gives the suitable complexes containing S-bonded ligands. Thioacylation of primary amines is reported, through a reaction in the coordinated ligands; the new ligands hold the coordination to the gold atom.

引用

页码：215 / 218

页数：4

共 11 条

[1]

Coucouvanis D., 1970, PROGR INORG CHEM, V11, P233, DOI 10.1002/9780470166123.ch4

[2] AU(III) COMPLEXES OF TRIS-DITHIOCARBAMATE DERIVATIVES OF ALPHA-AMINO-ACIDS - SPECTROSCOPIC STUDIES, THERMAL-BEHAVIOR AND ANTIBACTERIAL ACTIVITY [J].

CRIADO, JJ ;

LOPEZARIAS, JA ;

MACIAS, B ;

FERNANDEZLAGO, LR ;

SALAS, JM .

INORGANICA CHIMICA ACTA, 1992, 193 (02) :229-235

[3]

GARIN J, 1981, SYNTHESIS-STUTTGART, P961

[4] SULFUR-CONTAINING GOLD(III) CHELATES AND THEIR USE IN HETEROVALENT DIMER SYNTHESIS - CRYSTAL-STRUCTURES OF AUIII[CH2P(S)PH2]2BR,[AUIII[S2P(OH)PH]2]CL, AND AUIII[CH2P(S)PH2][S2CN(ET)2]2 [J].

MURRAY, HH ;

GARZON, G ;

RAPTIS, RG ;

MAZANY, AM ;

PORTER, LC ;

FACKLER, JP .

INORGANIC CHEMISTRY, 1988, 27 (05) :836-842

[5]

Noordik J. H., 1973, CRYSTAL STRUCTURE CO, V2, P81

[6]

PUDDEPHATT RJ, 1978, CHEM GOLD, P53

[7]

SCHEITHAUER S, 1979, TOP SULFUR CHEM, V4, P225

[8]

THORN GD, 1962, DITHIOCARBAMATES REL, P169

[9] PENTAFLUOROPHENYL(DITHIOCARBAMATE)GOLD(III) COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF (C6F5)2AU(S2CN(CH2PH)2) [J].

USON, R ;

LAGUNA, A ;

LAGUNA, M ;

CASTILLA, ML ;

JONES, PG ;

MEYERBASE, K .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 336 (03) :453-460

[10] PREPARATION AND PROPERTIES OF STABLE SALTS CONTAINING MONO-(PENTAFLUOROPHENYL)AURATE(I) OR BIS-(PENTAFLUOROPHENYL)AURATE(I) AND MONO-(PENTAFLUOROPHENYL)AURATE(III), TRIS-(PENTAFLUOROPHENYL)AURATE(III), OR TETRAKIS-(PENTAFLUOROPHENYL)AURATE(III) IONS [J].

USON, R ;

LAGUNA, A ;

VICENTE, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (10) :353-354

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