LITHIUM INCORPORATION BY VANADIUM PENTOXIDE

被引：326

作者：

MURPHY, DW

CHRISTIAN, PA

DISALVO, FJ

WASZCZAK, JV

机构：

[1] Bell Telephone Laboratories, Murray Hill

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 10期

关键词：

D O I：

10.1021/ic50200a034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of solid V2O5 with a solution of lithium iodide in acetonitrile at room temperature affords a series of bronzes, LixV2OP5 (0 <x ≤1.0), distinct from those with the same composition prepared above 300°C. The structures of these bronzes appear to be closely related to that of V2O5. In these bronzes V2O5 acts as a three-dimensional framework host for lithium. Magnetic susceptibility, X-ray powder diffraction, and DSC data for the bronzes are reported. © 1979, American Chemical Society. All rights reserved.

引用

页码：2800 / 2803

页数：4

共 25 条

[1]

Bachmann H. G., 1961, Z KRISTALLOGR, V115, P110, DOI DOI 10.1524/ZKRI.1961.115.1-2.110

[2] CHROMIUM OXIDES AS CATHODES FOR SECONDARY HIGH-ENERGY DENSITY LITHIUM BATTERIES [J].