SOLID-STATE C-13 NMR-SPECTROSCOPY .2. TITANIUM TETRACHLORIDE-KETONE COMPLEXES - STRUCTURE AND MECHANISM OF ISOMERIZATION

被引：2

作者：

MAIER, G ^{[1
]}

KALINOWSKI, HO ^{[1
]}

WEBER, C ^{[1
]}

HENRICH, M ^{[1
]}

机构：

[1] UNIV GIESSEN,INST ORGAN CHEM,D-35392 GIESSEN,GERMANY

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1995年 / 33卷 / 04期

关键词：

NMR; SOLID-STATE C-13 NMR; TITANIUM TETRACHLORIDE KETONE COMPLEXES; SYN-ANTI ISOMERIZATION; PLANAR INVERSION;

D O I：

10.1002/mrc.1260330412

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solid-state C-13 NMR spectra of a series of titanium tetrachloride-ketone and titanium tetrachloride-ester complexes are presented. The kind of complexation is discussed. The activation energy and the mechanism (planar inversion) for the syn-anti isomerization at the oxygen atom was evaluated.

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页码：290 / 296

页数：7

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