ADDITION OF ALKENES TO TRICARBONYL(VINYLKETENE)IRON(O) COMPLEXES AND THE SYNTHESIS OF CYCLOPROPANES

被引：26

作者：

SABERI, SP

SLAWIN, AMZ

THOMAS, SE

WILLIAMS, DJ

WARD, MF

WORTHINGTON, PA

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,CHEM CRYSTALLOG LAB,LONDON SW7 2AY,ENGLAND

[3] ZENECA AGROCHEM,JEALOTTS HILL RES STN,BRACKNELL RG12 6EY,BERKS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 18期

关键词：

D O I：

10.1039/c39940002169

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tricarbonyl(vinylketene)iron(o) complex 1 reacts with electron-poor alkenes to give decarbonylated adducts 3 and these are oxidised to tetrasubstituted cyclopropanes 4 using CAN; an X-ray crystal structure. analysis of the adduct formed from 1 and dimethyl fumarate define its relative stereochemistry.

引用

页码：2169 / 2170

页数：2

共 16 条

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