Deactivation of Hg(6(3)P(0))

被引：12

作者：

Callear, A. B. ^{[1
]}

McGurk, J. C. ^{[1
]}

机构：

[1] Phys Chem Lab, Cambridge, England

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 05期

关键词：

D O I：

10.1016/0009-2614(70)85180-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The excitation of Hg vapour/N-2 mixtures by a black-body Hash was shown to produce N(2)A(3)Sigma(+)(u) by double pumping. The decay of Hg(6(3)P(0)) following the flash therefore is not characteristic of the deactivation rate, since Hg(6(3)P(0)) is still produced after the flash by energy transfer from N(2)A(3)Sigma(+)(u). It is claimed that excitation of Hg vapour/N-2 mixtures with a new flash device was effectively uncomplicated; the derived cross-sections for deactivation of Hg(6(3)P(0)) were found to be much greater than previous estimates with the standard flash technique.

引用

页码：417 / 418

页数：2

共 5 条

[1] Rates of energy transfer from N(2)A(3)Sigma(+)(u) to atomic mercury and nitric oxide [J].

Callear, A. B. ;

Wood, P. M. .

CHEMICAL PHYSICS LETTERS, 1970, 5 (03) :128-130

[2] METASTABLE TRIPLET STATE OF MERCURY, HG6(3P0) - A STUDY OF ITS REACTIONS BY KINETIC SPECTROSCOPY [J].

CALLEAR, AB ;

NORRISH, RGW .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1962, 266 (1326) :299-&

[3] CROSS-SECTIONS FOR DEACTIVATION OF HG(63PO) [J].

CALLEAR, AB ;

WILLIAMS, GJ .

TRANSACTIONS OF THE FARADAY SOCIETY, 1964, 60 (504P) :2158-&

[4] FLASH SPECTROSCOPY WITH MERCURY RESONANCE RADIATION .1. AN EXPERIMENTAL METHOD WITH MICROWAVE-PULSE EXCITATION [J].

CALLEAR, AB ;

HEDGES, REM .

TRANSACTIONS OF THE FARADAY SOCIETY, 1970, 66 (567) :605-&

[5]

CALLEAR AB, 1970, NATURE, V266, P844

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