ROOM-TEMPERATURE SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF MONOCLINIC LICUO2 BY X-RAY AND NEUTRON-DIFFRACTION

被引：32

作者：

BERGER, R

TERGENIUS, LE

机构：

[1] Institute of Chemistry, University of Uppsala, S-751 21 Uppsala

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1994年 / 203卷 / 1-2期

关键词：

D O I：

10.1016/0925-8388(94)90736-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

LiCuO2 was synthesized at room temperature by delithiation of Li2CuO2 using bromine in acetonitrile. The product shows broad diffraction profiles which were analysed by the Rietveld refinement technique on X-ray and neutron powder data. The phase conforms to the NaCuO2 structure type (C2/m, Z = 2) with the cell a = 5.733(1) angstrom, b = 2.7176(3) angstrom, c = 5.622(1) angstrom, beta = 120.68(2)-degrees.

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页码：203 / 207

页数：5

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