THERMALLY-INDUCED ONE-STEP CONSTRUCTION OF THE TETRACYCLIC STEROIDAL SKELETON FROM ACYCLIC ENYNE ALLENES

被引：37

作者：

ANDEMICHAEL, YW ^{[1
]}

HUANG, Y ^{[1
]}

WANG, KK ^{[1
]}

机构：

[1] W VIRGINIA UNIV,DEPT CHEM,MORGANTOWN,WV 26506

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 07期

关键词：

D O I：

10.1021/jo00059a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

On heating, acyclic enyne-allenes 5 underwent a sequence of intramolecular transformations with a cascade of energy to produce 9 having the tetracyclic steroidal skeleton in a single step.

引用

页码：1651 / 1652

页数：2

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