THE SYNTHESIS OF WATER-SOLUBLE HEMIPORPHYRAZINE ANALOGS

被引：3

作者：

GEIGER, DK

SCHMIDT, RG

机构：

[1] Department of Chemistry, State University of New York, College at Geneseo, Geneseo

来源：

INORGANICA CHIMICA ACTA | 1992年 / 197卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)84966-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a new class of water-soluble tetradentate macrocyclic complexes is reported. A hemiporphyrazine derivatized with pyridine groups about the periphery has been prepared. The copper(II) and nickel(II) complexes were synthesized from the free-base ligand. The peripheral pyridine groups of the free ligand and the metal complexes have been methylated to yield complexes exhibiting appreciable water solubility. Visible absorption spectra and cyclic voltammetric data are reported.

引用

页码：203 / 207

页数：5