ASYMMETRIC INDUCTION STUDIES IN THE INTRAMOLECULAR PAUSON-KHAND CYCLIZATION OF 7-ALKOXY-1-HEPTEN-6-YNES

被引：50
作者：
POCH, M
VALENTI, E
MOYANO, A
PERICAS, MA
CASTRO, J
DENICOLA, A
GREENE, AE
机构：
[1] UNIV BARCELONA,DEPT QUIM ORGAN,MARTI & FRANQUES 1-11,E-08028 BARCELONA,SPAIN
[2] UNIV J FOURIER,LEDSS,F-38041 GRENOBLE,FRANCE
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 51期
关键词：
D O I：
10.1016/S0040-4039(00)88530-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Asymmetric induction has been achieved in the intramolecular Pauson-Khand reaction of 7-alkoxy-1-hepten-6-ynes derived from chiral alcohols. The stereochemical outcome of the reaction can be explained by the intermediacy of a cis-cobaltabicyclooctane.
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页码：7505 / 7508
页数：4
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