THE 1ST METAL METAL SILYL MIGRATION IN A HETEROBIMETALLIC COMPLEX, AND THE STRUCTURE OF THE REARRANGEMENT PRODUCT [(OC)4FE(MU-PPH2)PT(SI(OME)3)(PPH3)](FE-PT)

被引：51

作者：

BRAUNSTEIN, P ^{[1
]}

KNORR, M ^{[1
]}

HIRLE, B ^{[1
]}

REINHARD, G ^{[1
]}

SCHUBERT, U ^{[1
]}

机构：

[1] UNIV WURZBURG,INST ANORGAN CHEM,W-8700 WURZBURG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 12期

关键词：

D O I：

10.1002/anie.199215831

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Si-Pt bond is the result of the migration of a silyl ligand from one metal center to another. This rearrangement was proven for the first time for 1 a and 1 b and is highly dependent on the ligands. This is illustrated by the observations that lb could be isolated as a solid and in solution rearranges much slower than 1 a and that analogous complexes like 1 c do not isomerize.

引用

页码：1583 / 1585

页数：3

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