AQUEOUS PHOTOLYSIS OF NAPROPAMIDE

被引:15
作者
CHANG, LL [1 ]
GIANG, BY [1 ]
LEE, KS [1 ]
TSENG, CK [1 ]
机构
[1] ICI AMERICAS INC,WESTERN RES CTR,DIV AGR PROD,1200 S 47TH ST,BOX NUMBER 4023,RICHMOND,CA 94804
关键词
D O I
10.1021/jf00003a036
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
Photolysis of napropamide [N,N-diethyl-2-(1-naphthalenyloxy) propanamide] has been examined at 25 degrees-C in aqueous solution buffered at pH 7 by using radiation from a xenon arc lamp. The pseudo-first-order photolysis half-life and rate constant were 5.7 min and 1.2 x 10(-1) min-1, respectively. Three major photodegradation products were produced in yields up to 20%, 27%, and 9%. The three photodegradation products were isolated by HPLC and their structures identified by NMR and mass spectrometry.
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页码:617 / 621
页数:5
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